Adam Skrzecz 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -3 6e-03 Mass fraction (1) 1 6 1 -1 9.94e-01 Mass fraction (2) 3 9.94 1 -4 3e-04 Mass fraction (3) 1 3 1 1 -2 1.1e-02 Mole fraction - Liquid (1) 2 1.1 1 -1 9.88e-01 Mole fraction - Liquid (3) 3 9.88 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -2 1.1e-02 Mass fraction (1) 2 1.1 1 -1 9.89e-01 Mass fraction (2) 3 9.89 1 -4 4e-04 Mass fraction (3) 1 4 1 2 -2 2.0e-02 Mole fraction - Liquid (1) 2 2.0 1 -1 9.79e-01 Mole fraction - Liquid (3) 3 9.79 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -2 2.1e-02 Mass fraction (1) 2 2.1 1 -1 9.78e-01 Mass fraction (2) 3 9.78 1 -4 6e-04 Mass fraction (3) 1 6 1 3 -2 3.7e-02 Mole fraction - Liquid (1) 2 3.7 1 -1 9.61e-01 Mole fraction - Liquid (3) 3 9.61 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -2 3.6e-02 Mass fraction (1) 2 3.6 1 -1 9.63e-01 Mass fraction (2) 3 9.63 1 -4 7e-04 Mass fraction (3) 1 7 1 4 -2 6.3e-02 Mole fraction - Liquid (1) 2 6.3 1 -1 9.34e-01 Mole fraction - Liquid (3) 3 9.34 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -2 5.8e-02 Mass fraction (1) 2 5.8 1 -1 9.41e-01 Mass fraction (2) 3 9.41 1 -4 8e-04 Mass fraction (3) 1 8 1 5 -1 1.00e-01 Mole fraction - Liquid (1) 3 1.00 1 -1 8.97e-01 Mole fraction - Liquid (3) 3 8.97 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -2 6.1e-02 Mass fraction (1) 2 6.1 1 -1 9.38e-01 Mass fraction (2) 3 9.38 1 -4 8e-04 Mass fraction (3) 1 8 1 6 -1 1.05e-01 Mole fraction - Liquid (1) 3 1.05 1 -1 8.92e-01 Mole fraction - Liquid (3) 3 8.92 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -3 4e-03 Mass fraction (1) 1 4 1 -1 9.96e-01 Mass fraction (2) 3 9.96 1 -4 4e-04 Mass fraction (3) 1 4 1 7 -3 7e-03 Mole fraction - Liquid (1) 1 7 1 -1 9.91e-01 Mole fraction - Liquid (3) 3 9.91 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -3 8e-03 Mass fraction (1) 1 8 1 -1 9.91e-01 Mass fraction (2) 3 9.91 1 -4 6e-04 Mass fraction (3) 1 6 1 8 -2 1.4e-02 Mole fraction - Liquid (1) 2 1.4 1 -1 9.84e-01 Mole fraction - Liquid (3) 3 9.84 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 1.1e-02 Mass fraction (1) 2 1.1 1 -1 9.88e-01 Mass fraction (2) 3 9.88 1 -4 7e-04 Mass fraction (3) 1 7 1 9 -2 2.0e-02 Mole fraction - Liquid (1) 2 2.0 1 -1 9.78e-01 Mole fraction - Liquid (3) 3 9.78 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 1.3e-02 Mass fraction (1) 2 1.3 1 -1 9.86e-01 Mass fraction (2) 3 9.86 1 -4 8e-04 Mass fraction (3) 1 8 1 10 -2 2.3e-02 Mole fraction - Liquid (1) 2 2.3 1 -1 9.74e-01 Mole fraction - Liquid (3) 3 9.74 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 2.3e-02 Mass fraction (1) 2 2.3 1 -1 9.76e-01 Mass fraction (2) 3 9.76 1 -3 1e-03 Mass fraction (3) 1 1 1 11 -2 4.1e-02 Mole fraction - Liquid (1) 2 4.1 1 -1 9.56e-01 Mole fraction - Liquid (3) 3 9.56 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 3.4e-02 Mass fraction (1) 2 3.4 1 -1 9.65e-01 Mass fraction (2) 3 9.65 1 -3 1e-03 Mass fraction (3) 1 1 1 12 -2 6.0e-02 Mole fraction - Liquid (1) 2 6.0 1 -1 9.37e-01 Mole fraction - Liquid (3) 3 9.37 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 4.7e-02 Mass fraction (1) 2 4.7 1 -1 9.51e-01 Mass fraction (2) 3 9.51 1 -3 1.5e-03 Mass fraction (3) 2 1.5 1 13 -2 8.2e-02 Mole fraction - Liquid (1) 2 8.2 1 -1 9.14e-01 Mole fraction - Liquid (3) 3 9.14 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -2 7.1e-02 Mass fraction (1) 2 7.1 1 -1 9.27e-01 Mass fraction (2) 3 9.27 1 -3 2e-03 Mass fraction (3) 1 2 1 14 -1 1.21e-01 Mole fraction - Liquid (1) 3 1.21 1 -1 8.73e-01 Mole fraction - Liquid (3) 3 8.73 1 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -1 7.07e-01 Mass fraction (1) 3 7.07 1 -2 1.5e-02 Mass fraction (2) 2 1.5 1 1 -1 5.84e-01 Mole fraction - Liquid (1) 3 5.84 1 -3 7e-03 Mole fraction - Liquid (2) 1 7 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -1 8.05e-01 Mass fraction (1) 3 8.05 1 -2 3.9e-02 Mass fraction (2) 2 3.9 1 2 -1 7.29e-01 Mole fraction - Liquid (1) 3 7.29 1 -2 1.9e-02 Mole fraction - Liquid (2) 2 1.9 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -1 8.34e-01 Mass fraction (1) 3 8.34 1 -2 8.2e-02 Mass fraction (2) 2 8.2 1 3 -1 8.11e-01 Mole fraction - Liquid (1) 3 8.11 1 -2 4.4e-02 Mole fraction - Liquid (2) 2 4.4 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -1 8.24e-01 Mass fraction (1) 3 8.24 1 -1 1.30e-01 Mass fraction (2) 3 1.30 1 4 -1 8.43e-01 Mole fraction - Liquid (1) 3 8.43 1 -2 7.3e-02 Mole fraction - Liquid (2) 2 7.3 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -1 7.72e-01 Mass fraction (1) 3 7.72 1 -1 2.06e-01 Mass fraction (2) 3 2.06 1 5 -1 8.35e-01 Mole fraction - Liquid (1) 3 8.35 1 -1 1.23e-01 Mole fraction - Liquid (2) 3 1.23 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.732e+02 Ambient temperature 4 2.732 $\pu{K}$ -1 7.64e-01 Mass fraction (1) 3 7.64 1 -1 2.18e-01 Mass fraction (2) 3 2.18 1 6 -1 8.34e-01 Mole fraction - Liquid (1) 3 8.34 1 -1 1.31e-01 Mole fraction - Liquid (2) 3 1.31 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 3.96e-01 Mass fraction (1) 3 3.96 1 -3 3e-03 Mass fraction (2) 1 3 1 7 -1 2.70e-01 Mole fraction - Liquid (1) 3 2.70 1 -3 1e-03 Mole fraction - Liquid (2) 1 1 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 6.44e-01 Mass fraction (1) 3 6.44 1 -2 1.1e-02 Mass fraction (2) 2 1.1 1 8 -1 5.10e-01 Mole fraction - Liquid (1) 3 5.10 1 -3 5e-03 Mole fraction - Liquid (2) 1 5 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.37e-01 Mass fraction (1) 3 7.37 1 -2 2.2e-02 Mass fraction (2) 2 2.2 1 9 -1 6.26e-01 Mole fraction - Liquid (1) 3 6.26 1 -2 1.0e-02 Mole fraction - Liquid (2) 2 1.0 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.53e-01 Mass fraction (1) 3 7.53 1 -2 2.7e-02 Mass fraction (2) 2 2.7 1 10 -1 6.50e-01 Mole fraction - Liquid (1) 3 6.50 1 -2 1.3e-02 Mole fraction - Liquid (2) 2 1.3 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.97e-01 Mass fraction (1) 3 7.97 1 -2 4.6e-02 Mass fraction (2) 2 4.6 1 11 -1 7.23e-01 Mole fraction - Liquid (1) 3 7.23 1 -2 2.3e-02 Mole fraction - Liquid (2) 2 2.3 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.87e-01 Mass fraction (1) 3 7.87 1 -1 1.05e-01 Mass fraction (2) 3 1.05 1 12 -1 7.59e-01 Mole fraction - Liquid (1) 3 7.59 1 -2 5.6e-02 Mole fraction - Liquid (2) 2 5.6 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 7.68e-01 Mass fraction (1) 3 7.68 1 -1 1.63e-01 Mass fraction (2) 3 1.63 1 13 -1 7.83e-01 Mole fraction - Liquid (1) 3 7.83 1 -2 9.2e-02 Mole fraction - Liquid (2) 2 9.2 1 1 2.00e+01 Ambient temperature 3 2.00 °C 2 2.932e+02 Ambient temperature 4 2.932 $\pu{K}$ -1 6.75e-01 Mass fraction (1) 3 6.75 1 -1 2.89e-01 Mass fraction (2) 3 2.89 1 14 -1 7.51e-01 Mole fraction - Liquid (1) 3 7.51 1 -1 1.77e-01 Mole fraction - Liquid (2) 3 1.77 1 2 Solubility, Solubility data series The analytical method was used, similar to that reported in [1]. Samples of each phase were analyzed by GLC on a 3 mm diameter by 3 m long column packed with Poropak R and using $\ce{H2}$ as a carrier gas. Each sample was injected several times and the composition was determined from chromatogram areas. Care was taken to avoid contamination by the surroundings, especially water vapor. The International Union of Pure and Applied Chemistry Ishida, K.; Bull. Chem. Soc. Jpn. 29, 956 (1956). paper https://doi.org/10.1246/bcsj.29.956 Noda, K.; Sato, K.; Nagatsuka, K.; Ishida, K.; J. Chem. Eng. Jpn. 8, 492-3 (1975). paper https://doi.org/10.1252/jcej.8.492 67-56-1 1 CH4O InChI=1S/CH4O/c1-2/h2H,1H3 OKKJLVBELUTLKV-UHFFFAOYSA-N 32.0419 Methanol Takachiho Chemical Industry Co., Ltd; standard reagent; used as received. 7732-18-5 3 H2O InChI=1S/H2O/h1H2 XLYOFNOQVPJJNP-UHFFFAOYSA-N 18.0153 Water Distilled 106-97-8 2 C4H10 InChI=1S/C4H10/c1-3-4-2/h3-4H2,1-2H3 IJDNQMDRQITEOD-UHFFFAOYSA-N 58.1222 Butane Methanol with n-Butane and water