{"compilation": {"title": "Solubility data from IUPAC SDS Volume 69 (page ?) - Methanol with n-Butane and water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Adam Skrzecz", "sources": [{"citation": "Noda, K.; Sato, K.; Nagatsuka, K.; Ishida, K.; J. Chem. Eng. Jpn. 8, 492-3 (1975).", "pubtype": "paper", "url": "https://doi.org/10.1252/jcej.8.492"}], "system": "Methanol with n-Butane and water", "substances": [{"constituent": 1, "name": "Methanol", "formula": "CH4O", "molweight": 32.0419, "casrn": "67-56-1", "inchi": "InChI=1S/CH4O/c1-2/h2H,1H3", "inchikey": "OKKJLVBELUTLKV-UHFFFAOYSA-N", "sample": "Takachiho Chemical Industry Co., Ltd; standard reagent; used as received."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled"}, {"constituent": 2, "name": "Butane", "formula": "C4H10", "molweight": 58.1222, "casrn": "106-97-8", "inchi": "InChI=1S/C4H10/c1-3-4-2/h3-4H2,1-2H3", "inchikey": "IJDNQMDRQITEOD-UHFFFAOYSA-N"}], "method": "The analytical method was used, similar to that reported in [1]. Samples of each phase were analyzed by GLC on a 3 mm diameter by 3 m long column packed with Poropak R and using $\\ce{H2}$ as a carrier gas. Each sample was injected several times and the composition was determined from chromatogram areas. Care was taken to avoid contamination by the surroundings, especially water vapor.", "reference": {"citation": "Ishida, K.; Bull. Chem. Soc. Jpn. 29, 956 (1956).", "pubtype": "paper", "url": "https://doi.org/10.1246/bcsj.29.956"}, "dataset": [{"series": 1, "title": "Compositions of coexisting phases", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "0e+00", "significand": "0.0", "exponent": "0", "sigfigs": "0", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.732e+02", "significand": "2.732", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "6e-03", "significand": "6", "exponent": "-3", "sigfigs": "1", "unit": "1"}, {"property": "Mass fraction (2)", "number": "9.94e-01", "significand": "9.94", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (3)", "number": "3e-04", "significand": "3", "exponent": "-4", "sigfigs": "1", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "1.1e-02", "significand": "1.1", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - 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