Adam Skrzecz
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.932e+02
Ambient temperature
4
2.932
$\pu{K}$
-1
2.29e-01
Mole fraction - Liquid (1)
3
2.29
1
-1
7.62e-01
Mole fraction - Liquid (2)
3
7.62
1
1
-1
1.02e-01
Mass fraction (1)
3
1.02
1
-1
8.95e-01
Mass fraction (2)
3
8.95
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.932e+02
Ambient temperature
4
2.932
$\pu{K}$
-1
3.92e-01
Mole fraction - Liquid (1)
3
3.92
1
-1
5.93e-01
Mole fraction - Liquid (2)
3
5.93
1
2
-1
2.00e-01
Mass fraction (1)
3
2.00
1
-1
7.95e-01
Mass fraction (2)
3
7.95
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.932e+02
Ambient temperature
4
2.932
$\pu{K}$
-1
5.13e-01
Mole fraction - Liquid (1)
3
5.13
1
-1
4.65e-01
Mole fraction - Liquid (2)
3
4.65
1
3
-1
2.94e-01
Mass fraction (1)
3
2.94
1
-1
6.99e-01
Mass fraction (2)
3
6.99
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.932e+02
Ambient temperature
4
2.932
$\pu{K}$
-1
6.14e-01
Mole fraction - Liquid (1)
3
6.14
1
-1
3.57e-01
Mole fraction - Liquid (2)
3
3.57
1
4
-1
3.92e-01
Mass fraction (1)
3
3.92
1
-1
5.98e-01
Mass fraction (2)
3
5.98
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.932e+02
Ambient temperature
4
2.932
$\pu{K}$
-1
6.90e-01
Mole fraction - Liquid (1)
3
6.90
1
-1
2.75e-01
Mole fraction - Liquid (2)
3
2.75
1
5
-1
4.82e-01
Mass fraction (1)
3
4.82
1
-1
5.04e-01
Mass fraction (2)
3
5.04
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.932e+02
Ambient temperature
4
2.932
$\pu{K}$
-1
7.46e-01
Mole fraction - Liquid (1)
3
7.46
1
-1
2.03e-01
Mole fraction - Liquid (2)
3
2.03
1
6
-1
5.70e-01
Mass fraction (1)
3
5.70
1
-1
4.08e-01
Mass fraction (2)
3
4.08
1
1
Compositions along the saturation curve
Solubility, Solubility data series
The titration method was used to determine binodal curve. The synthetic method was used to determine phase equilibra. The mole fraction of hydrocarbon in the charge before separation was about 0.30. After separation phases were analyzed by GLC to determine methanol and hydrocarbon; concentration of water was determined by Karl Fischer method.
The International Union of Pure and Applied Chemistry
Budantseva, L. S.; Lesteva, T. M.; Nemstov, M. S.; Zh. Fiz. Khim. 1976, 50, 1344.
paper
67-56-1
1
CH4O
InChI=1S/CH4O/c1-2/h2H,1H3
OKKJLVBELUTLKV-UHFFFAOYSA-N
32.0419
Methanol
Source not specified.
592-41-6
2
C6H12
InChI=1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
LIKMAJRDDDTEIG-UHFFFAOYSA-N
84.1595
1-Hexene
Source not specified; distilled; purity >99.9%.
7732-18-5
3
H2O
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
18.0153
Water
Source not specified.
Methanol with 1-Hexene and Water
Solubility data from IUPAC SDS Volume 69 (page ?) - Methanol with 1-Hexene and Water