{"compilation": {"title": "Solubility data from IUPAC SDS Volume 69 (page ?) - Methanol with 1-Hexene and Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Adam Skrzecz", "sources": [{"citation": "Budantseva, L. S.; Lesteva, T. M.; Nemstov, M. S.; Zh. Fiz. Khim. 1976, 50, 1344.", "pubtype": "paper"}], "system": "Methanol with 1-Hexene and Water", "substances": [{"constituent": 1, "name": "Methanol", "formula": "CH4O", "molweight": 32.0419, "casrn": "67-56-1", "inchi": "InChI=1S/CH4O/c1-2/h2H,1H3", "inchikey": "OKKJLVBELUTLKV-UHFFFAOYSA-N", "sample": "Source not specified."}, {"constituent": 2, "name": "1-Hexene", "formula": "C6H12", "molweight": 84.1595, "casrn": "592-41-6", "inchi": "InChI=1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3", "inchikey": "LIKMAJRDDDTEIG-UHFFFAOYSA-N", "sample": "Source not specified; distilled; purity >99.9%."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source not specified."}], "method": "The titration method was used to determine binodal curve. The synthetic method was used to determine phase equilibra. The mole fraction of hydrocarbon in the charge before separation was about 0.30. After separation phases were analyzed by GLC to determine methanol and hydrocarbon; concentration of water was determined by Karl Fischer method.", "dataset": [{"series": 1, "title": "Compositions along the saturation curve", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.29e-01", "significand": "2.29", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "7.62e-01", "significand": "7.62", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mass fraction (1)", "number": "1.02e-01", "significand": "1.02", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "8.95e-01", "significand": "8.95", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "3.92e-01", "significand": "3.92", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "5.93e-01", "significand": "5.93", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mass fraction (1)", "number": "2.00e-01", "significand": "2.00", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "7.95e-01", "significand": "7.95", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.13e-01", "significand": "5.13", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.65e-01", "significand": "4.65", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mass fraction (1)", "number": "2.94e-01", "significand": "2.94", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "6.99e-01", "significand": "6.99", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - 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