Adam Skrzecz
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-2
2.45e-02
Mass fraction (1)
3
2.45
1
-1
9.750e-01
Mass fraction (2)
4
9.750
1
1
-2
3.70e-02
Mole fraction - Liquid (1)
3
3.70
1
-1
9.605e-01
Mole fraction - Liquid (2)
4
9.605
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-2
7.20e-02
Mass fraction (1)
3
7.20
1
-1
9.230e-01
Mass fraction (2)
4
9.230
1
2
-1
1.042e-01
Mole fraction - Liquid (1)
4
1.042
1
-1
8.716e-01
Mole fraction - Liquid (2)
4
8.716
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.185e-01
Mass fraction (1)
4
1.185
1
-1
8.715e-01
Mass fraction (2)
4
8.715
1
3
-1
1.645e-01
Mole fraction - Liquid (1)
4
1.645
1
-1
7.892e-01
Mole fraction - Liquid (2)
4
7.892
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.050e-01
Mass fraction (1)
4
2.050
1
-1
7.730e-01
Mass fraction (2)
4
7.730
1
4
-1
2.620e-01
Mole fraction - Liquid (1)
4
2.620
1
-1
6.443e-01
Mole fraction - Liquid (2)
4
6.443
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.520e-01
Mass fraction (1)
4
2.520
1
-1
7.190e-01
Mass fraction (2)
4
7.190
1
5
-1
3.082e-01
Mole fraction - Liquid (1)
4
3.082
1
-1
5.735e-01
Mole fraction - Liquid (2)
4
5.735
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.080e-01
Mass fraction (1)
4
3.080
1
-1
6.500e-01
Mass fraction (2)
4
6.500
1
6
-1
3.532e-01
Mole fraction - Liquid (1)
4
3.532
1
-1
4.861e-01
Mole fraction - Liquid (2)
4
4.861
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.890e-01
Mass fraction (1)
4
3.890
1
-1
5.445e-01
Mass fraction (2)
4
5.445
1
7
-1
4.027e-01
Mole fraction - Liquid (1)
4
4.027
1
-1
3.676e-01
Mole fraction - Liquid (2)
4
3.676
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.835e-01
Mass fraction (1)
4
4.835
1
-1
4.070e-01
Mass fraction (2)
4
4.070
1
8
-1
4.339e-01
Mole fraction - Liquid (1)
4
4.339
1
-1
2.382e-01
Mole fraction - Liquid (2)
4
2.382
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
5.015e-01
Mass fraction (1)
4
5.015
1
-1
3.760e-01
Mass fraction (2)
4
3.760
1
9
-1
4.341e-01
Mole fraction - Liquid (1)
4
4.341
1
-1
2.123e-01
Mole fraction - Liquid (2)
4
2.123
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
5.590e-01
Mass fraction (1)
4
5.590
1
-1
2.520e-01
Mass fraction (2)
4
2.520
1
10
-1
4.129e-01
Mole fraction - Liquid (1)
4
4.129
1
-1
1.214e-01
Mole fraction - Liquid (2)
4
1.214
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
5.665e-01
Mass fraction (1)
4
5.665
1
-1
1.750e-01
Mass fraction (2)
4
1.750
1
11
-1
3.672e-01
Mole fraction - Liquid (1)
4
3.672
1
-2
7.40e-02
Mole fraction - Liquid (2)
3
7.40
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-2
8.20e-02
Mass fraction (1)
3
8.20
1
-3
5.0e-03
Mass fraction (2)
2
5.0
1
12
-2
2.62e-02
Mole fraction - Liquid (1)
3
2.62
1
-3
1.0e-03
Mole fraction - Liquid (2)
2
1.0
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.180e-01
Mass fraction (1)
4
1.180
1
-3
4.5e-03
Mass fraction (2)
2
4.5
1
13
-2
3.87e-02
Mole fraction - Liquid (1)
3
3.87
1
-3
1.0e-03
Mole fraction - Liquid (2)
2
1.0
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.400e-01
Mass fraction (1)
4
1.400
1
-3
5.0e-03
Mass fraction (2)
2
5.0
1
14
-2
4.67e-02
Mole fraction - Liquid (1)
3
4.67
1
-3
1.1e-03
Mole fraction - Liquid (2)
2
1.1
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.470e-01
Mass fraction (1)
4
1.470
1
-3
4.0e-03
Mass fraction (2)
2
4.0
1
15
-2
4.93e-02
Mole fraction - Liquid (1)
3
4.93
1
-4
9e-04
Mole fraction - Liquid (2)
1
9
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.550e-01
Mass fraction (1)
4
1.550
1
-3
5.0e-03
Mass fraction (2)
2
5.0
1
16
-2
5.24e-02
Mole fraction - Liquid (1)
3
5.24
1
-3
1.1e-03
Mole fraction - Liquid (2)
2
1.1
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.590e-01
Mass fraction (1)
4
1.590
1
-3
2.5e-03
Mass fraction (2)
2
2.5
1
17
-2
5.38e-02
Mole fraction - Liquid (1)
3
5.38
1
-4
6e-04
Mole fraction - Liquid (2)
1
6
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.170e-01
Mass fraction (1)
4
1.170
1
-3
2.8e-03
Mass fraction (2)
2
2.8
1
18
-2
6.07e-02
Mole fraction - Liquid (1)
3
6.07
1
-4
6e-04
Mole fraction - Liquid (2)
1
6
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.910e-01
Mass fraction (1)
4
1.910
1
-3
3.5e-03
Mass fraction (2)
2
3.5
1
19
-2
6.63e-02
Mole fraction - Liquid (1)
3
6.63
1
-4
8e-04
Mole fraction - Liquid (2)
1
8
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.930e-01
Mass fraction (1)
4
1.930
1
-3
4.0e-03
Mass fraction (2)
2
4.0
1
20
-2
6.71e-02
Mole fraction - Liquid (1)
3
6.71
1
-4
9e-04
Mole fraction - Liquid (2)
1
9
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.220e-01
Mass fraction (1)
4
2.220
1
-3
5.5e-03
Mass fraction (2)
2
5.5
1
21
-2
7.92e-02
Mole fraction - Liquid (1)
3
7.92
1
-3
1.3e-03
Mole fraction - Liquid (2)
2
1.3
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.240e-01
Mass fraction (1)
4
2.240
1
-3
6.0e-03
Mass fraction (2)
2
6.0
1
22
-2
8.01e-02
Mole fraction - Liquid (1)
3
8.01
1
-3
1.4e-03
Mole fraction - Liquid (2)
2
1.4
1
2
Compositions of coexisting phases
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-2
8.493e-02
Mass fraction (1)
4
8.493
1
-1
9.1016e-01
Mass fraction (2)
5
9.1016
1
1
-1
1.2221e-01
Mole fraction - Liquid (1)
5
1.2221
1
-1
8.5422e-01
Mole fraction - Liquid (2)
5
8.5422
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.0297e-01
Mass fraction (1)
5
1.0297
1
-1
8.8978e-01
Mass fraction (2)
5
8.8978
1
2
-1
1.4554e-01
Mole fraction - Liquid (1)
5
1.4554
1
-1
8.2027e-01
Mole fraction - Liquid (2)
5
8.2027
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.3190e-01
Mass fraction (1)
5
1.3190
1
-1
8.5784e-01
Mass fraction (2)
5
8.5784
1
3
-1
1.8177e-01
Mole fraction - Liquid (1)
5
1.8177
1
-1
7.7106e-01
Mole fraction - Liquid (2)
5
7.7106
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.8300e-01
Mass fraction (1)
5
1.8300
1
-1
7.9913e-01
Mass fraction (2)
5
7.9913
1
4
-1
2.3959e-01
Mole fraction - Liquid (1)
5
2.3959
1
-1
6.8237e-01
Mole fraction - Liquid (2)
5
6.8237
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.5906e-01
Mass fraction (1)
5
2.5906
1
-1
7.1136e-01
Mass fraction (2)
5
7.1136
1
5
-1
3.1527e-01
Mole fraction - Liquid (1)
5
3.1527
1
-1
5.6464e-01
Mole fraction - Liquid (2)
5
5.6464
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.0104e-01
Mass fraction (1)
5
3.0104
1
-1
6.5742e-01
Mass fraction (2)
5
6.5742
1
6
-1
3.4666e-01
Mole fraction - Liquid (1)
5
3.4666
1
-1
4.9377e-01
Mole fraction - Liquid (2)
5
4.9377
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.6001e-01
Mass fraction (1)
5
3.6001
1
-1
5.8484e-01
Mass fraction (2)
5
5.8484
1
7
-1
3.8902e-01
Mole fraction - Liquid (1)
5
3.8902
1
-1
4.1218e-01
Mole fraction - Liquid (2)
5
4.1218
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.4089e-01
Mass fraction (1)
5
4.4089
1
-1
4.7442e-01
Mass fraction (2)
5
4.7442
1
8
-1
4.2688e-01
Mole fraction - Liquid (1)
5
4.2688
1
-1
2.9959e-01
Mole fraction - Liquid (2)
5
2.9959
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.7820e-01
Mass fraction (1)
5
4.7820
1
-1
4.1460e-01
Mass fraction (2)
5
4.1460
1
9
-1
4.3229e-01
Mole fraction - Liquid (1)
5
4.3229
1
-1
2.4445e-01
Mole fraction - Liquid (2)
5
2.4445
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
5.4526e-01
Mass fraction (1)
5
5.4526
1
-1
2.9663e-01
Mass fraction (2)
5
2.9663
1
10
-1
4.3064e-01
Mole fraction - Liquid (1)
5
4.3064
1
-1
1.5280e-01
Mole fraction - Liquid (2)
5
1.5280
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
5.6596e-01
Mass fraction (1)
5
5.6596
1
-1
1.8299e-01
Mass fraction (2)
5
1.8299
1
11
-1
3.7167e-01
Mole fraction - Liquid (1)
5
3.7167
1
-2
7.838e-02
Mole fraction - Liquid (2)
4
7.838
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
5.3954e-01
Mass fraction (1)
5
5.3954
1
-1
1.1697e-01
Mass fraction (2)
5
1.1697
1
12
-1
3.0627e-01
Mole fraction - Liquid (1)
5
3.0627
1
-2
4.331e-02
Mole fraction - Liquid (2)
4
4.331
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.2525e-01
Mass fraction (1)
5
4.2525
1
-2
4.573e-02
Mass fraction (2)
4
4.573
1
13
-1
1.9157e-01
Mole fraction - Liquid (1)
5
1.9157
1
-2
1.344e-02
Mole fraction - Liquid (2)
4
1.344
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.0295e-01
Mass fraction (1)
5
3.0295
1
-2
1.855e-02
Mass fraction (2)
4
1.855
1
14
-1
1.1750e-01
Mole fraction - Liquid (1)
5
1.1750
1
-3
4.69e-03
Mole fraction - Liquid (2)
3
4.69
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.2653e-01
Mass fraction (1)
5
2.2653
1
-3
6.09e-03
Mass fraction (2)
3
6.09
1
15
-2
8.118e-02
Mole fraction - Liquid (1)
4
8.118
1
-3
1.42e-03
Mole fraction - Liquid (2)
3
1.42
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.0969e-01
Mass fraction (1)
5
2.0969
1
-3
4.44e-03
Mass fraction (2)
3
4.44
1
16
-2
7.399e-02
Mole fraction - Liquid (1)
4
7.399
1
-3
1.02e-03
Mole fraction - Liquid (2)
3
1.02
1
1
Compositions along the saturation curve
Solubility, Solubility data series
The titration and analytical methods were used. Weighed portions of 1-propanol and toluene in glass stoppered flasks were titrated with water from a calibrated burette. After each portion of water the mixture was shaken and the temperature of the solution was allowed to return to 25 °C before further additions of water. When the end-point was reached, the mixture was left in the bath for 30 min before specific gravity and refractive index were determined. The binary two liquid-phase mixtures of toluene and water were treated with 1-propanol and when equilibrium was reached the samples of each layer were removed and refractive indexes were determined. A large-scale graph of refractive index, constructed during the binodal curve determinations, was used to find equilibrium concentrations.
The International Union of Pure and Applied Chemistry
Baker, E. M.; J. Phys. Chem. 59, 1182 (1955).
paper
https://doi.org/10.1021/j150533a017
71-23-8
1
C3H8O
InChI=1S/C3H8O/c1-2-3-4/h4H,2-3H2,1H3
BDERNNFJNOPAEC-UHFFFAOYSA-N
60.095
1-Propanol
Eastman Kodak Co., distilled over $\ce{CaCI2}$, middle fraction was used;<br/>$d_{4}^{25} = \pu{0.79999 \pm 0.0002}$, $n_{D}^{25} = \pu{1.3854 \pm 0.0001}$.
108-88-3
2
C7H8
InChI=1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3
YXFVVABEGXRONW-UHFFFAOYSA-N
92.1384
Toluene
Source not specified; analytical reagent grade; dried over sodium, distilled;<br/>$d_{4}^{25} = \pu{0.85939 \pm 0.0002}$, $n_{D}^{25} = \pu{1.3325 \pm 0.0001}$.
7732-18-5
3
H2O
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
18.0153
Water
Distilled from alkaline potassium permanganate.
1-Proponal with Toluene and Water
Solubility data from IUPAC SDS Volume 69 (page ?) - 1-Proponal with Toluene and Water