Adam Skrzecz 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -4 8e-04 Mass fraction (1) 1 8 1 -1 9.931e-01 Mass fraction (2) 4 9.931 1 1 -3 1.5e-03 Mole fraction - Liquid (1) 2 1.5 1 -1 9.700e-01 Mole fraction - Liquid (2) 4 9.700 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -2 1.75e-02 Mass fraction (1) 3 1.75 1 -1 9.771e-01 Mass fraction (2) 4 9.771 1 2 -2 3.16e-02 Mole fraction - Liquid (1) 3 3.16 1 -1 9.434e-01 Mole fraction - Liquid (2) 4 9.434 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 3.767e-01 Mass fraction (1) 4 3.767 1 -3 2.3e-03 Mass fraction (2) 2 2.3 1 3 -1 1.916e-01 Mole fraction - Liquid (1) 4 1.916 1 -4 6e-04 Mole fraction - Liquid (2) 1 6 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 5.692e-01 Mass fraction (1) 4 5.692 1 -2 2.91e-02 Mass fraction (2) 3 2.91 1 4 -1 3.531e-01 Mole fraction - Liquid (1) 4 3.531 1 -3 9.7e-03 Mole fraction - Liquid (2) 2 9.7 1 2 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -2 6.53e-02 Mass fraction (1) 3 6.53 1 -1 9.270e-01 Mass fraction (2) 4 9.270 1 1 -1 1.125e-01 Mole fraction - Liquid (1) 4 1.125 1 -1 8.536e-01 Mole fraction - Liquid (2) 4 8.536 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 4.430e-01 Mass fraction (1) 4 4.430 1 -1 5.410e-01 Mass fraction (2) 4 5.410 1 2 -1 5.730e-01 Mole fraction - Liquid (1) 4 5.730 1 -1 3.741e-01 Mole fraction - Liquid (2) 4 3.741 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 5.332e-01 Mass fraction (1) 4 5.332 1 -1 4.539e-01 Mass fraction (2) 4 4.539 1 3 -1 6.592e-01 Mole fraction - Liquid (1) 4 6.592 1 -1 3.000e-01 Mole fraction - Liquid (2) 4 3.000 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 6.334e-01 Mass fraction (1) 4 6.334 1 -1 3.518e-01 Mass fraction (2) 4 3.518 1 4 -1 7.371e-01 Mole fraction - Liquid (1) 4 7.371 1 -1 2.189e-01 Mole fraction - Liquid (2) 4 2.189 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 7.401e-01 Mass fraction (1) 4 7.401 1 -1 2.167e-01 Mass fraction (2) 4 2.167 1 5 -1 7.658e-01 Mole fraction - Liquid (1) 4 7.658 1 -1 1.199e-01 Mole fraction - Liquid (2) 4 1.199 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 7.922e-01 Mass fraction (1) 4 7.922 1 -1 1.186e-01 Mass fraction (2) 4 1.186 1 6 -1 7.310e-01 Mole fraction - Liquid (1) 4 7.310 1 -2 5.85e-02 Mole fraction - Liquid (2) 3 5.85 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 7.874e-01 Mass fraction (1) 4 7.874 1 -2 7.96e-02 Mass fraction (2) 3 7.96 1 7 -1 6.730e-01 Mole fraction - Liquid (1) 4 6.730 1 -2 3.64e-02 Mole fraction - Liquid (2) 3 3.64 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 7.908e-01 Mass fraction (1) 4 7.908 1 -2 7.32e-02 Mass fraction (2) 3 7.32 1 8 -1 6.715e-01 Mole fraction - Liquid (1) 4 6.715 1 -2 3.32e-02 Mole fraction - Liquid (2) 3 3.32 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 7.682e-01 Mass fraction (1) 4 7.682 1 -2 4.00e-02 Mass fraction (2) 3 4.00 1 9 -1 6.001e-01 Mole fraction - Liquid (1) 4 6.001 1 -2 1.67e-02 Mole fraction - Liquid (2) 3 1.67 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 6.985e-01 Mass fraction (1) 4 6.985 1 -2 2.13e-02 Mass fraction (2) 3 2.13 1 10 -1 4.897e-01 Mole fraction - Liquid (1) 4 4.897 1 -3 8.0e-03 Mole fraction - Liquid (2) 2 8.0 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 6.943e-01 Mass fraction (1) 4 6.943 1 -2 1.57e-02 Mass fraction (2) 3 1.57 1 11 -1 4.807e-01 Mole fraction - Liquid (1) 4 4.807 1 -3 5.8e-03 Mole fraction - Liquid (2) 2 5.8 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 6.004e-01 Mass fraction (1) 4 6.004 1 -3 9.4e-03 Mass fraction (2) 2 9.4 1 12 -1 3.745e-01 Mole fraction - Liquid (1) 4 3.745 1 -3 3.1e-03 Mole fraction - Liquid (2) 2 3.1 1 0 0e+00 Ambient temperature 0 0.0 °C 2 2.7315e+02 Ambient temperature 5 2.7315 $\pu{K}$ -1 4.312e-01 Mass fraction (1) 4 4.312 1 -3 4.2e-03 Mass fraction (2) 2 4.2 1 13 -1 2.297e-01 Mole fraction - Liquid (1) 4 2.297 1 -3 1.2e-03 Mole fraction - Liquid (2) 2 1.2 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -2 3.10e-02 Mass fraction (1) 3 3.10 1 -1 9.592e-01 Mass fraction (2) 4 9.592 1 14 -2 5.45e-02 Mole fraction - Liquid (1) 3 5.45 1 -1 9.014e-01 Mole fraction - Liquid (2) 4 9.014 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 1.852e-01 Mass fraction (1) 4 1.852 1 -1 7.997e-01 Mass fraction (2) 4 7.997 1 15 -1 2.843e-01 Mole fraction - Liquid (1) 4 2.843 1 -1 6.564e-01 Mole fraction - Liquid (2) 4 6.564 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 3.628e-01 Mass fraction (1) 4 3.628 1 -1 6.164e-01 Mass fraction (2) 4 6.164 1 16 -1 4.866e-01 Mole fraction - Liquid (1) 4 4.866 1 -1 4.420e-01 Mole fraction - Liquid (2) 4 4.420 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 3.782e-01 Mass fraction (1) 4 3.782 1 -1 5.970e-01 Mass fraction (2) 4 5.970 1 17 -1 4.971e-01 Mole fraction - Liquid (1) 4 4.971 1 -1 4.195e-01 Mole fraction - Liquid (2) 4 4.195 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 5.194e-01 Mass fraction (1) 4 5.194 1 -1 4.591e-01 Mass fraction (2) 4 4.591 1 18 -1 6.336e-01 Mole fraction - Liquid (1) 4 6.336 1 -1 2.994e-01 Mole fraction - Liquid (2) 4 2.994 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 6.803e-01 Mass fraction (1) 4 6.803 1 -1 2.811e-01 Mass fraction (2) 4 2.811 1 19 -1 7.321e-01 Mole fraction - Liquid (1) 4 7.321 1 -1 1.617e-01 Mole fraction - Liquid (2) 4 1.617 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.384e-01 Mass fraction (1) 4 7.384 1 -1 1.761e-01 Mass fraction (2) 4 1.761 1 20 -1 7.024e-01 Mole fraction - Liquid (1) 4 7.024 1 -2 8.96e-02 Mole fraction - Liquid (2) 3 8.96 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.473e-01 Mass fraction (1) 4 7.473 1 -1 1.293e-01 Mass fraction (2) 4 1.293 1 21 -1 6.602e-01 Mole fraction - Liquid (1) 4 6.602 1 -2 6.11e-02 Mole fraction - Liquid (2) 3 6.11 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.352e-01 Mass fraction (1) 4 7.352 1 -2 8.00e-02 Mass fraction (2) 3 8.00 1 22 -1 5.879e-01 Mole fraction - Liquid (1) 4 5.879 1 -2 3.42e-02 Mole fraction - Liquid (2) 3 3.42 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 6.749e-01 Mass fraction (1) 4 6.749 1 -2 3.61e-02 Mass fraction (2) 3 3.61 1 23 -1 4.709e-01 Mole fraction - Liquid (1) 4 4.709 1 -2 1.35e-02 Mole fraction - Liquid (2) 3 1.35 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 5.381e-01 Mass fraction (1) 4 5.381 1 -2 1.86e-02 Mass fraction (2) 3 1.86 1 24 -1 3.200e-01 Mole fraction - Liquid (1) 4 3.200 1 -3 5.9e-03 Mole fraction - Liquid (2) 2 5.9 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 3.668e-01 Mass fraction (1) 4 3.668 1 -2 1.21e-02 Mass fraction (2) 3 1.21 1 25 -1 1.870e-01 Mole fraction - Liquid (1) 4 1.870 1 -3 3.3e-03 Mole fraction - Liquid (2) 2 3.3 1 1 Solubility, Solubility data series A titration method similar to that in [1] was used. A flask of 100 mL capacity containing a binary hexane-alcohol mixture of known composition, by weight, was placed in a thermostat. The mixture was titrated with water from a microburette with a scale of 0.01 mL, until opalescence, emulation or turbidity was observed. Samples of the same binary composition were titrated several times. Compositions of coexisting phases were obtained by an analytical method similar to that in [12]. Experimental points were located on the binodal curve obtained by the authors. The ternary mixture became homogeneous when the hexane concentration reached 79.4 mass % at 0 °C and 74.73 mass % at 25 °C. The International Union of Pure and Applied Chemistry Tarasenkov, D. N.; Polozhentseva, E. N.; Zh. Obshch. Khim. 2, 84 (1932). paper Tarasenkov, D. N.; Paulsen, I. A.; Zh. Obshch. Khim. 7, 2143 (1937). paper 64-17-5 1 C2H6O InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3 LFQSCWFLJHTTHZ-UHFFFAOYSA-N 46.0684 Ethanol Source not specified; purity of 99.97% for three points of the lower alcohol concentration at each temperature and purity of 92.64% for all other points. 110-54-3 2 C6H14 InChI=1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3 VLKZOEOYAKHREP-UHFFFAOYSA-N 86.1754 Hexane Source not specified; distilled; BP = 68.65°C, $d_{4}^{20}$ = 0.6898. 7732-18-5 3 H2O InChI=1S/H2O/h1H2 XLYOFNOQVPJJNP-UHFFFAOYSA-N 18.0153 Water Source not specified. Ethanol with n-Hexane with Water