{"compilation": {"title": "Solubility data from IUPAC SDS Volume 68 (page ?) - 1-Bromobutane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Gross, P. M.; Saylor, J. H.; J. Am. Chem. Soc. 1931, 53, 1744-51.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01356a016"}], "system": "1-Bromobutane with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "distilled."}, {"constituent": 1, "name": "1-Bromobutane", "formula": "C4H9Br", "molweight": 137.018, "casrn": "109-65-9", "inchi": "InChI=1S/C4H9Br/c1-2-3-4-5/h2-4H2,1H3", "inchikey": "MPPPKRYCTPRNTB-UHFFFAOYSA-N", "sample": "Eastman Kodak Company. Purified by fractional distillation before use."}], "method": "An excess of 1-bromobutane in 500 g water was shaken for 12 hours in a waterbath thermostat. Samples were then withdrawn and read against pure water in an interferometer made by Zeiss [1]. A detailed description of the complete procedure is given in a Ph.D. thesis [2].", "reference": {"citation": "Saylor, J. H.; Ph.D. Dissertation, Duke University, Durham, NC, 1930.", "pubtype": "dissertation"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "6.08e-04", "significand": "6.08", "exponent": "-4", "sigfigs": "3", "unit": "g<sub>1</sub>/g<sub>2</sub>"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "6.08e-02", "significand": "6.08", "exponent": "-2", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "8.00e-05", "significand": "8.00", "exponent": "-5", "sigfigs": "3", "unit": "1"}]}]}]}}