Adam Skrzecz
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.503e-01
Mole fraction - Liquid (1)
4
2.503
1
-1
6.653e-01
Mole fraction - Liquid (2)
4
6.653
1
1
-1
1.22e-01
Mass fraction (1)
3
1.22
1
-1
8.68e-01
Mass fraction (2)
3
8.68
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.533e-01
Mole fraction - Liquid (1)
4
2.533
1
-1
6.474e-01
Mole fraction - Liquid (2)
4
6.474
1
2
-1
1.26e-01
Mass fraction (1)
3
1.26
1
-1
8.62e-01
Mass fraction (2)
3
8.62
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.684e-01
Mole fraction - Liquid (1)
4
2.684
1
-1
6.335e-01
Mole fraction - Liquid (2)
4
6.335
1
3
-1
1.35e-01
Mass fraction (1)
3
1.35
1
-1
8.53e-01
Mass fraction (2)
3
8.53
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.737e-01
Mole fraction - Liquid (1)
4
2.737
1
-1
6.359e-01
Mole fraction - Liquid (2)
4
6.359
1
4
-1
1.37e-01
Mass fraction (1)
3
1.37
1
-1
8.52e-01
Mass fraction (2)
3
8.52
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.786e-01
Mole fraction - Liquid (1)
4
2.786
1
-1
6.313e-01
Mole fraction - Liquid (2)
4
6.313
1
5
-1
1.40e-01
Mass fraction (1)
3
1.40
1
-1
8.49e-01
Mass fraction (2)
3
8.49
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.819e-01
Mole fraction - Liquid (1)
4
2.819
1
-1
6.282e-01
Mole fraction - Liquid (2)
4
6.282
1
6
-1
1.42e-01
Mass fraction (1)
3
1.42
1
-1
8.47e-01
Mass fraction (2)
3
8.47
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.835e-01
Mole fraction - Liquid (1)
4
2.835
1
-1
6.267e-01
Mole fraction - Liquid (2)
4
6.267
1
7
-1
1.43e-01
Mass fraction (1)
3
1.43
1
-1
8.46e-01
Mass fraction (2)
3
8.46
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.922e-01
Mole fraction - Liquid (1)
4
2.922
1
-1
6.260e-01
Mole fraction - Liquid (2)
4
6.260
1
8
-1
1.47e-01
Mass fraction (1)
3
1.47
1
-1
8.43e-01
Mass fraction (2)
3
8.43
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.954e-01
Mole fraction - Liquid (1)
4
2.954
1
-1
6.230e-01
Mole fraction - Liquid (2)
4
6.230
1
9
-1
1.49e-01
Mass fraction (1)
3
1.49
1
-1
8.41e-01
Mass fraction (2)
3
8.41
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.003e-01
Mole fraction - Liquid (1)
4
3.003
1
-1
6.185e-01
Mole fraction - Liquid (2)
4
6.185
1
10
-1
1.52e-01
Mass fraction (1)
3
1.52
1
-1
8.38e-01
Mass fraction (2)
3
8.38
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.019e-01
Mole fraction - Liquid (1)
4
3.019
1
-1
6.170e-01
Mole fraction - Liquid (2)
4
6.170
1
11
-1
1.53e-01
Mass fraction (1)
3
1.53
1
-1
8.37e-01
Mass fraction (2)
3
8.37
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.668e-01
Mole fraction - Liquid (1)
4
3.668
1
-1
4.529e-01
Mole fraction - Liquid (2)
4
4.529
1
12
-1
2.26e-01
Mass fraction (1)
3
2.26
1
-1
7.47e-01
Mass fraction (2)
3
7.47
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.807e-01
Mole fraction - Liquid (1)
4
3.807
1
-1
4.308e-01
Mole fraction - Liquid (2)
4
4.308
1
13
-1
2.41e-01
Mass fraction (1)
3
2.41
1
-1
7.30e-01
Mass fraction (2)
3
7.30
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
3.974e-01
Mole fraction - Liquid (1)
4
3.974
1
-1
4.070e-01
Mole fraction - Liquid (2)
4
4.070
1
14
-1
2.59e-01
Mass fraction (1)
3
2.59
1
-1
7.10e-01
Mass fraction (2)
3
7.10
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.108e-01
Mole fraction - Liquid (1)
4
4.108
1
-1
3.818e-01
Mole fraction - Liquid (2)
4
3.818
1
15
-1
2.77e-01
Mass fraction (1)
3
2.77
1
-1
6.89e-01
Mass fraction (2)
3
6.89
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.439e-01
Mole fraction - Liquid (1)
4
4.439
1
-1
3.250e-01
Mole fraction - Liquid (2)
4
3.250
1
16
-1
3.24e-01
Mass fraction (1)
3
3.24
1
-1
6.35e-01
Mass fraction (2)
3
6.35
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.415e-01
Mole fraction - Liquid (1)
4
1.415
1
-4
4e-04
Mole fraction - Liquid (2)
1
4
1
17
-1
4.03e-01
Mass fraction (1)
3
4.03
1
-3
3e-03
Mass fraction (2)
1
3
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.530e-01
Mole fraction - Liquid (1)
4
1.530
1
-4
8e-04
Mole fraction - Liquid (2)
1
8
1
18
-1
4.24e-01
Mass fraction (1)
3
4.24
1
-3
6e-03
Mass fraction (2)
1
6
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
1.983e-01
Mole fraction - Liquid (1)
4
1.983
1
-3
2.4e-03
Mole fraction - Liquid (2)
2
2.4
1
19
-1
4.97e-01
Mass fraction (1)
3
4.97
1
-2
1.6e-02
Mass fraction (2)
2
1.6
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.038e-01
Mole fraction - Liquid (1)
4
2.038
1
-3
2.3e-03
Mole fraction - Liquid (2)
2
2.3
1
20
-1
5.06e-01
Mass fraction (1)
3
5.06
1
-2
1.5e-02
Mass fraction (2)
2
1.5
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.129e-01
Mole fraction - Liquid (1)
4
2.129
1
-3
2.5e-03
Mole fraction - Liquid (2)
2
2.5
1
21
-1
5.19e-01
Mass fraction (1)
3
5.19
1
-2
1.6e-02
Mass fraction (2)
2
1.6
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.212e-01
Mole fraction - Liquid (1)
4
2.212
1
-3
2.5e-03
Mole fraction - Liquid (2)
2
2.5
1
22
-1
5.31e-01
Mass fraction (1)
3
5.31
1
-2
1.6e-02
Mass fraction (2)
2
1.6
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.229e-01
Mole fraction - Liquid (1)
4
2.229
1
-3
2.7e-03
Mole fraction - Liquid (2)
2
2.7
1
23
-1
5.33e-01
Mass fraction (1)
3
5.33
1
-2
1.7e-02
Mass fraction (2)
2
1.7
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.447e-01
Mole fraction - Liquid (1)
4
2.447
1
-3
3.3e-03
Mole fraction - Liquid (2)
2
3.3
1
24
-1
5.61e-01
Mass fraction (1)
3
5.61
1
-2
2.0e-02
Mass fraction (2)
2
2.0
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.506e-01
Mole fraction - Liquid (1)
4
2.506
1
-3
3.5e-03
Mole fraction - Liquid (2)
2
3.5
1
25
-1
5.68e-01
Mass fraction (1)
3
5.68
1
-2
2.1e-02
Mass fraction (2)
2
2.1
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.602e-01
Mole fraction - Liquid (1)
4
2.602
1
-3
3.9e-03
Mole fraction - Liquid (2)
2
3.9
1
26
-1
5.79e-01
Mass fraction (1)
3
5.79
1
-2
2.3e-02
Mass fraction (2)
2
2.3
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
2.651e-01
Mole fraction - Liquid (1)
4
2.651
1
-3
3.9e-03
Mole fraction - Liquid (2)
2
3.9
1
27
-1
5.85e-01
Mass fraction (1)
3
5.85
1
-2
2.3e-02
Mass fraction (2)
2
2.3
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.110e-01
Mole fraction - Liquid (1)
4
4.110
1
-2
1.96e-02
Mole fraction - Liquid (2)
3
1.96
1
28
-1
6.83e-01
Mass fraction (1)
3
6.83
1
-2
8.7e-02
Mass fraction (2)
2
8.7
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.306e-01
Mole fraction - Liquid (1)
4
4.306
1
-2
2.34e-02
Mole fraction - Liquid (2)
3
2.34
1
29
-1
6.68e-01
Mass fraction (1)
3
6.68
1
-1
1.00e-01
Mass fraction (2)
3
1.00
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.460e-01
Mole fraction - Liquid (1)
4
4.460
1
-2
2.89e-02
Mole fraction - Liquid (2)
3
2.89
1
30
-1
6.85e-01
Mass fraction (1)
3
6.85
1
-1
1.19e-01
Mass fraction (2)
3
1.19
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.577e-01
Mole fraction - Liquid (1)
4
4.577
1
-2
3.48e-02
Mole fraction - Liquid (2)
3
3.48
1
31
-1
6.79e-01
Mass fraction (1)
3
6.79
1
-1
1.38e-01
Mass fraction (2)
3
1.38
1
1
2.50e+01
Ambient temperature
3
2.50
°C
2
2.982e+02
Ambient temperature
4
2.982
$\pu{K}$
-1
4.834e-01
Mole fraction - Liquid (1)
4
4.834
1
-2
5.03e-02
Mole fraction - Liquid (2)
3
5.03
1
32
-1
6.61e-01
Mass fraction (1)
3
6.61
1
-1
1.84e-01
Mass fraction (2)
3
1.84
1
1
Compositions of coexisting phases
Solubility, Solubility data series
The analytical method was used. Mixtures containing approximately equal volumes of each phase, in vials capped with Teflon-lined septa were vigorously shaken and then allowed to equilibrate at least 24 h in a thermostated water bath. Six to 14 GLC analyses [1] with ethanol as the internal standard, were performed on each sample. Reported concentrations of each component were bounded by estimated 95% confidence interval, but the sum of mass fraction differed from 1.000.
The International Union of Pure and Applied Chemistry
Silva, M. K.; Ph.D. Dissertation, University of Kansas, Lawrence, KS, 1990.
dissertation
Silva, M. K.; Michnick, M. J.; Willhite, G. P.; Fluid Phase Equilib. 59, 247-262 (1990).
paper
https://doi.org/10.1016/0378-3812(90)80002-s
75-65-0
1
C4H10O
InChI=1S/C4H10O/c1-4(2,3)5/h5H,1-3H3
DKGAVHZHDRPRBM-UHFFFAOYSA-N
74.1216
2-Methyl-2-propanol
Fischer Scientific, certified; used as received; purity >99 wt%, verified by GLC.
629-59-4
2
C14H30
InChI=1S/C14H30/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-14H2,1-2H3
BGHCVCJVXZWKCC-UHFFFAOYSA-N
198.388
Tetradecane
Aldrich, certified; used as received; purity >99 wt%, verified by GLC.
7732-18-5
3
H2O
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
18.0153
Water
De-ionized and distilled, sodium concentration <0.025 ppm sodium.
2-Methyl-2-propanol with n-Tetradecane and Water
Solubility data from IUPAC SDS Volume 69 (page ?) - 2-Methyl-2-propanol with n-Tetradecane and Water