{"compilation": {"title": "Solubility data from IUPAC SDS Volume 69 (page ?) - 2-Methyl-2-propanol with n-Tetradecane and Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Adam Skrzecz", "sources": [{"citation": "Silva, M. K.; Michnick, M. J.; Willhite, G. P.; Fluid Phase Equilib. 59, 247-262 (1990).", "pubtype": "paper", "url": "https://doi.org/10.1016/0378-3812(90)80002-s"}], "system": "2-Methyl-2-propanol with n-Tetradecane and Water", "substances": [{"constituent": 1, "name": "2-Methyl-2-propanol", "formula": "C4H10O", "molweight": 74.1216, "casrn": "75-65-0", "inchi": "InChI=1S/C4H10O/c1-4(2,3)5/h5H,1-3H3", "inchikey": "DKGAVHZHDRPRBM-UHFFFAOYSA-N", "sample": "Fischer Scientific, certified; used as received; purity >99 wt%, verified by GLC."}, {"constituent": 2, "name": "Tetradecane", "formula": "C14H30", "molweight": 198.388, "casrn": "629-59-4", "inchi": "InChI=1S/C14H30/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-14H2,1-2H3", "inchikey": "BGHCVCJVXZWKCC-UHFFFAOYSA-N", "sample": "Aldrich, certified; used as received; purity >99 wt%, verified by GLC."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "De-ionized and distilled, sodium concentration <0.025 ppm sodium."}], "method": "The analytical method was used. Mixtures containing approximately equal volumes of each phase, in vials capped with Teflon-lined septa were vigorously shaken and then allowed to equilibrate at least 24 h in a thermostated water bath. Six to 14 GLC analyses [1] with ethanol as the internal standard, were performed on each sample. Reported concentrations of each component were bounded by estimated 95% confidence interval, but the sum of mass fraction differed from 1.000.", "reference": {"citation": "Silva, M. K.; Ph.D. Dissertation, University of Kansas, Lawrence, KS, 1990.", "pubtype": "dissertation"}, "dataset": [{"series": 1, "title": "Compositions of coexisting phases", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}, {"property": "Ambient temperature", "number": "2.982e+02", "significand": "2.982", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.503e-01", "significand": "2.503", "exponent": "-1", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "6.653e-01", "significand": "6.653", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Mass fraction (1)", "number": "1.22e-01", "significand": "1.22", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "8.68e-01", "significand": "8.68", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}, {"property": "Ambient temperature", "number": "2.982e+02", "significand": "2.982", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - 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