Adam Skrzecz 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 1.086e-01 Mass fraction (1) 4 1.086 1 -1 8.903e-01 Mass fraction (2) 4 8.903 1 -1 2.372e-01 Mole fraction - Liquid (1) 4 2.372 1 -1 7.585e-01 Mole fraction - Liquid (2) 4 7.585 1 1 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 2.065e-01 Mass fraction (1) 4 2.065 1 -1 7.909e-01 Mass fraction (2) 4 7.909 1 -1 3.974e-01 Mole fraction - Liquid (1) 4 3.974 1 -1 5.937e-01 Mole fraction - Liquid (2) 4 5.937 1 2 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 3.143e-01 Mass fraction (1) 4 3.143 1 -1 6.809e-01 Mass fraction (2) 4 6.809 1 -1 5.341e-01 Mole fraction - Liquid (1) 4 5.341 1 -1 4.514e-01 Mole fraction - Liquid (2) 4 4.514 1 3 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 4.235e-01 Mass fraction (1) 4 4.235 1 -1 5.688e-01 Mass fraction (2) 4 5.688 1 -1 6.426e-01 Mole fraction - Liquid (1) 4 6.426 1 -1 3.366e-01 Mole fraction - Liquid (2) 4 3.366 1 4 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 5.430e-01 Mass fraction (1) 4 5.430 1 -1 4.413e-01 Mass fraction (2) 4 4.413 1 -1 7.308e-01 Mole fraction - Liquid (1) 4 7.308 1 -1 2.317e-01 Mole fraction - Liquid (2) 4 2.317 1 5 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 6.631e-01 Mass fraction (1) 4 6.631 1 -1 3.020e-01 Mass fraction (2) 4 3.020 1 -1 7.866e-01 Mole fraction - Liquid (1) 4 7.866 1 -1 1.397e-01 Mole fraction - Liquid (2) 4 1.397 1 6 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.404e-01 Mass fraction (1) 4 7.404 1 -1 1.787e-01 Mass fraction (2) 4 1.787 1 -1 7.761e-01 Mole fraction - Liquid (1) 4 7.761 1 -2 7.31e-02 Mole fraction - Liquid (2) 3 7.31 1 7 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.611e-01 Mass fraction (1) 4 7.611 1 -1 1.067e-01 Mass fraction (2) 4 1.067 1 -1 7.333e-01 Mole fraction - Liquid (1) 4 7.333 1 -2 4.01e-02 Mole fraction - Liquid (2) 3 4.01 1 8 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.436e-01 Mass fraction (1) 4 7.436 1 -2 6.57e-02 Mass fraction (2) 3 6.57 1 -1 6.709e-01 Mole fraction - Liquid (1) 4 6.709 1 -2 2.31e-02 Mole fraction - Liquid (2) 3 2.31 1 9 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 7.079e-01 Mass fraction (1) 4 7.079 1 -2 3.52e-02 Mass fraction (2) 3 3.52 1 -1 6.007e-01 Mole fraction - Liquid (1) 4 6.007 1 -2 1.17e-02 Mole fraction - Liquid (2) 3 1.17 1 10 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 6.456e-01 Mass fraction (1) 4 6.456 1 -2 2.05e-02 Mass fraction (2) 3 2.05 1 -1 5.175e-01 Mole fraction - Liquid (1) 4 5.175 1 -3 6.4e-03 Mole fraction - Liquid (2) 2 6.4 1 11 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 5.587e-01 Mass fraction (1) 4 5.587 1 -3 8.7e-03 Mass fraction (2) 2 8.7 1 -1 4.196e-01 Mole fraction - Liquid (1) 4 4.196 1 -3 2.5e-03 Mole fraction - Liquid (2) 2 2.5 1 12 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 4.796e-01 Mass fraction (1) 4 4.796 1 -3 4.8e-03 Mass fraction (2) 2 4.8 1 -1 3.429e-01 Mole fraction - Liquid (1) 4 3.429 1 -3 1.3e-03 Mole fraction - Liquid (2) 2 1.3 1 13 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 3.712e-01 Mass fraction (1) 4 3.712 1 -3 2.0e-03 Mass fraction (2) 2 2.0 1 -1 2.497e-01 Mole fraction - Liquid (1) 4 2.497 1 -4 5e-04 Mole fraction - Liquid (2) 1 5 1 14 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 2.492e-01 Mass fraction (1) 4 2.492 1 -3 1.0e-03 Mass fraction (2) 2 1.0 1 -1 1.574e-01 Mole fraction - Liquid (1) 4 1.574 1 -4 2e-04 Mole fraction - Liquid (2) 1 2 1 15 1 2.50e+01 Ambient temperature 3 2.50 °C 2 2.9815e+02 Ambient temperature 5 2.9815 $\pu{K}$ -1 1.531e-01 Mass fraction (1) 4 1.531 1 -4 5e-04 Mass fraction (2) 1 5 1 -2 9.23e-02 Mole fraction - Liquid (1) 3 9.23 1 -4 1e-04 Mole fraction - Liquid (2) 1 1 1 16 1 Solubility, Solubility data series The titration method, as described in [1], was used. The titrant, from a weighed pipette, was added to the weighed binary mixture of known composition and the mixture was kept in a thermostated bath. To confirm that the end-point was reached the mixture was shaken automatically for at least 15 min and then reexamined. The plot of refractive index against composition was then used to find compositions of equilibrium phases. The refractive indexes were determined at the temperature of 30.0 °C to eliminate an opalescene. The International Union of Pure and Applied Chemistry Washburn, E. R.; Beguin, A. E.; J. Am. Chem. Soc. 62, 579 (1940). paper https://doi.org/10.1021/ja01860a041 Washburn, E. R.; Graham, C. L.; Arnold, G. B.; Transue, L. F.; J. Am. Chem. Soc. 62, 1454 (1940). paper https://doi.org/10.1021/ja01863a036 67-56-1 1 CH4O InChI=1S/CH4O/c1-2/h2H,1H3 OKKJLVBELUTLKV-UHFFFAOYSA-N 32.0419 Methanol Not specified. 7732-18-5 3 H2O InChI=1S/H2O/h1H2 XLYOFNOQVPJJNP-UHFFFAOYSA-N 18.0153 Water 110-83-8 2 C6H10 InChI=1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2 HGCIXCUEYOPUTN-UHFFFAOYSA-N 82.1436 Cyclohexene Eastman Kodak Company, commercial grade; distilled in an atmosphere of purified $\ce{N2}$, collected in dried nitrogen-filled bottles; $d_{4}^{25}$ = 0.8056, $n_{D}^{25}$ = 1.4434. Methanol with Cyclohexene and Water