{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4287/jsonld#"}], "@id": "", "generatedAt": "08-19-26 08:47:12", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4287/jsonld#", "@type": "sdo:scidataFramework", "uid": "71_226", "title": "Solubility data from IUPAC SDS Volume 71 (page ?) - Nitromethane with Hexadecanoic acid", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:K", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The synthetic method, as described in Broughton, [1] was used. Liquids were pipetted into glass tubes. Temperatures at which complete miscibility occurred were measured by thermometers standardized against a set of thermometers having NPL certificates.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Broughton, G.; Trans. Faraday Soc. 30, 367 (1934).", "doi": "10.1039/tf9343000367", "url": "https://doi.org/10.1039/tf9343000367"}, {"@id": "procedure/1/reference/2/", "@type": "sdo:reference", "number": 2, "citation": "Jones, D. C.; Betts, H. F.; J. Chem. Soc. 1177 (1928).", "doi": "10.1039/jr9280001177", "url": "https://doi.org/10.1039/jr9280001177"}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Nitromethane", "formula": "CH3NO2 ", "casrn": "75-52-5", "iupacname": "nitromethane", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Hexadecanoic acid", "formula": "C16H32O2", "casrn": "57-10-3", "iupacname": "hexadecanoic acid", "inchikey": "IPCSVZSSVZVIGE-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Nitromethane", "description": "Prepared from sodium monochloroacetate with sodium nitrite; distilled; $n_{D}^{25}$ = 1.3796, $\\rho^{25} = \\pu{1130.8 g L-1}$.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Hexadecanoic acid", "description": "Source not specified; purified according to Jones and Betts [2] (recrystallized from petrol ether and ethanol, MP = 62.6°C).", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitromethane with Hexadecanoic acid", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Kelvin", "unit#": "qudt:K"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.6555e+02", "significand": 3.6555, "exponent": 2, "sigfigs": 5}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.6720e+02", "significand": 3.672, "exponent": 2, "sigfigs": 5}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7365e+02", "significand": 3.7365, "exponent": 2, "sigfigs": 5}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7475e+02", "significand": 3.7475, "exponent": 2, "sigfigs": 5}, {"@id": "condition/5/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7480e+02", "significand": 3.748, "exponent": 2, "sigfigs": 5}, {"@id": "condition/6/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7590e+02", "significand": 3.759, "exponent": 2, "sigfigs": 5}, {"@id": "condition/7/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7670e+02", "significand": 3.767, "exponent": 2, "sigfigs": 5}, {"@id": "condition/8/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7710e+02", "significand": 3.771, "exponent": 2, "sigfigs": 5}, {"@id": "condition/9/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7730e+02", "significand": 3.773, "exponent": 2, "sigfigs": 5}, {"@id": "condition/10/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7745e+02", "significand": 3.7745, "exponent": 2, "sigfigs": 5}, {"@id": "condition/11/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7760e+02", "significand": 3.776, "exponent": 2, "sigfigs": 5}, {"@id": "condition/12/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7765e+02", "significand": 3.7765, "exponent": 2, "sigfigs": 5}, {"@id": "condition/13/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.7770e+02", "significand": 3.777, "exponent": 2, "sigfigs": 5}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/", "datapoint/7/", "datapoint/8/", "datapoint/9/", "datapoint/10/", "datapoint/11/", "datapoint/12/", "datapoint/13/", "datapoint/14/", "datapoint/15/", "datapoint/16/", "datapoint/17/", "datapoint/18/", "datapoint/19/", "datapoint/20/", "datapoint/21/", "datapoint/22/", "datapoint/23/", "datapoint/24/", "datapoint/25/", "datapoint/26/", "datapoint/27/", "datapoint/28/", "datapoint/29/", "datapoint/30/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "71:226:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.716e+01", "significand": 2.716, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.104e-01", "significand": 6.104, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "71:226:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "71:226:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "71:226:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.786e+01", "significand": 8.786, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.682e-01", "significand": 9.682, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "71:226:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.820e+01", "significand": 3.82, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.220e-01", "significand": 7.22, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "71:226:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/7/", "@type": "sdo:datapoint", "uid": "71:226:001:001:007", "conditions#": ["condition/7/"], "data": [{"@id": "datapoint/7/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/7/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/7/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/7/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/8/", "@type": "sdo:datapoint", "uid": "71:226:001:001:008", "conditions#": ["condition/8/"], "data": [{"@id": "datapoint/8/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/8/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.155e+01", "significand": 8.155, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/8/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/8/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.489e-01", "significand": 9.489, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/9/", "@type": "sdo:datapoint", "uid": "71:226:001:001:009", "conditions#": ["condition/9/"], "data": [{"@id": "datapoint/9/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/9/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.107e+01", "significand": 4.107, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/9/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/9/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.454e-01", "significand": 7.454, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/10/", "@type": "sdo:datapoint", "uid": "71:226:001:001:010", "conditions#": ["condition/10/"], "data": [{"@id": "datapoint/10/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/10/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/10/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/10/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/11/", "@type": "sdo:datapoint", "uid": "71:226:001:001:011", "conditions#": ["condition/11/"], "data": [{"@id": "datapoint/11/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/11/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/11/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/11/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/12/", "@type": "sdo:datapoint", "uid": "71:226:001:001:012", "conditions#": ["condition/12/"], "data": [{"@id": "datapoint/12/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/12/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.710e+01", "significand": 7.71, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/12/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/12/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.340e-01", "significand": 9.34, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/13/", "@type": "sdo:datapoint", "uid": "71:226:001:001:013", "conditions#": ["condition/13/"], "data": [{"@id": "datapoint/13/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/13/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.685e+01", "significand": 4.685, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/13/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/13/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.874e-01", "significand": 7.874, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/14/", "@type": "sdo:datapoint", "uid": "71:226:001:001:014", "conditions#": ["condition/14/"], "data": [{"@id": "datapoint/14/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/14/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/14/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/14/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/15/", "@type": "sdo:datapoint", "uid": "71:226:001:001:015", "conditions#": ["condition/15/"], "data": [{"@id": "datapoint/15/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/15/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/15/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/15/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/16/", "@type": "sdo:datapoint", "uid": "71:226:001:001:016", "conditions#": ["condition/16/"], "data": [{"@id": "datapoint/16/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/16/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.156e+01", "significand": 7.156, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/16/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/16/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.136e-01", "significand": 9.136, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/17/", "@type": "sdo:datapoint", "uid": "71:226:001:001:017", "conditions#": ["condition/17/"], "data": [{"@id": "datapoint/17/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/17/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/17/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/17/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/18/", "@type": "sdo:datapoint", "uid": "71:226:001:001:018", "conditions#": ["condition/18/"], "data": [{"@id": "datapoint/18/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/18/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.803e+01", "significand": 6.803, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/18/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/18/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.994e-01", "significand": 8.994, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/19/", "@type": "sdo:datapoint", "uid": "71:226:001:001:019", "conditions#": ["condition/19/"], "data": [{"@id": "datapoint/19/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/19/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/19/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/19/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/20/", "@type": "sdo:datapoint", "uid": "71:226:001:001:020", "conditions#": ["condition/20/"], "data": [{"@id": "datapoint/20/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/20/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.664e+01", "significand": 6.664, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/20/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/20/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.935e-01", "significand": 8.935, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/21/", "@type": "sdo:datapoint", "uid": "71:226:001:001:021", "conditions#": ["condition/21/"], "data": [{"@id": "datapoint/21/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/21/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/21/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/21/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/22/", "@type": "sdo:datapoint", "uid": "71:226:001:001:022", "conditions#": ["condition/22/"], "data": [{"@id": "datapoint/22/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/22/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.570e+01", "significand": 6.57, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/22/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/22/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.895e-01", "significand": 8.895, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/23/", "@type": "sdo:datapoint", "uid": "71:226:001:001:023", "conditions#": ["condition/23/"], "data": [{"@id": "datapoint/23/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/23/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.423e+01", "significand": 5.423, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/23/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/23/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.327e-01", "significand": 8.327, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/24/", "@type": "sdo:datapoint", "uid": "71:226:001:001:024", "conditions#": ["condition/24/"], "data": [{"@id": "datapoint/24/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/24/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/24/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/24/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/25/", "@type": "sdo:datapoint", "uid": "71:226:001:001:025", "conditions#": ["condition/25/"], "data": [{"@id": "datapoint/25/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/25/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.105e+01", "significand": 6.105, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/25/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/25/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.682e-01", "significand": 8.682, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/26/", "@type": "sdo:datapoint", "uid": "71:226:001:001:026", "conditions#": ["condition/26/"], "data": [{"@id": "datapoint/26/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/26/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/26/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/26/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/27/", "@type": "sdo:datapoint", "uid": "71:226:001:001:027", "conditions#": ["condition/27/"], "data": [{"@id": "datapoint/27/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/27/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.252e+01", "significand": 6.252, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/27/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/27/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.751e-01", "significand": 8.751, "exponent": -1, "sigfigs": 4}}]}, {"@id": "datapoint/28/", "@type": "sdo:datapoint", "uid": "71:226:001:001:028", "conditions#": ["condition/28/"], "data": [{"@id": "datapoint/28/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/28/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/28/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/28/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/29/", "@type": "sdo:datapoint", "uid": "71:226:001:001:029", "conditions#": ["condition/29/"], "data": [{"@id": "datapoint/29/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/29/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/29/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/29/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}, {"@id": "datapoint/30/", "@type": "sdo:datapoint", "uid": "71:226:001:001:030", "conditions#": ["condition/30/"], "data": [{"@id": "datapoint/30/datum/1/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/30/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/30/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/30/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Broughton, G.; Jones, D. C.; Trans. Faraday Soc. 32, 685-9 (1936).", "doi": "10.1039/tf9363200685", "url": "https://doi.org/10.1039/tf9363200685"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 71 (page ?) - Nitromethane with Hexadecanoic acid", "url": "https://doi.org/10.1063/1.1329911"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}