{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page ?) - Nitromethane with Cycloalkanes (C6, C7 and C10)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Francis, A. W.; Ind. Eng. Chem. 36, 1096-104 (1944).", "pubtype": "paper", "url": "https://doi.org/10.1021/ie50420a005"}], "system": "Nitromethane with Cycloalkanes (C6, C7 and C10)", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Source not specified; pure grade reagent."}, {"constituent": 2, "name": "Decahydronaphthalene", "formula": "C10H18", "molweight": 138.25, "casrn": "91-17-8", "inchi": "InChI=1S/C10H18/c1-2-6-10-8-4-3-7-9(10)5-1/h9-10H,1-8H2", "inchikey": "NNBZCPXTIHJBJL-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 2, "name": "Cyclohexane", "formula": "C6H12", "molweight": 84.1595, "casrn": "110-82-7", "inchi": "InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2", "inchikey": "XDTMQSROBMDMFD-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 2, "name": "Methylcyclohexane", "formula": "C7H14", "molweight": 98.1861, "casrn": "108-87-2", "inchi": "InChI=1S/C7H14/c1-7-5-3-2-4-6-7/h7H,2-6H2,1H3", "inchikey": "UAEPNZWRGJTJPN-UHFFFAOYSA-N", "sample": "Not specified."}], "method": "The synthetic method was used. The reagents, about 1 mL of (1) and 1 to 1.5 mL of (2), were placed in tubes and stirred with a thermometer while the tubes were warmed gradually in a bath of water or glycerol. The temperature of disappearance or reappearance of the cloud due to two liquid phases was read three or four times in each direction. If the final position of the interface was not near the middle of the liquid, the volumes of the reagents were adjusted to make it so.", "dataset": [{"series": 1, "title": "Critical solution temperatures of nitromethane and cycloalkane", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "7.9e+01", "significand": "7.9", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.52e+02", "significand": "3.52", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "8.08e+01", "significand": "8.08", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "9.0e+01", "significand": "9.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.63e+02", "significand": "3.63", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.008e+02", "significand": "1.008", "exponent": "2", "sigfigs": "4", "unit": "°C"}], "data": [], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "1.16e+02", "significand": "1.16", "exponent": "2", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.89e+02", "significand": "3.89", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.946e+02", "significand": "1.946", "exponent": "2", "sigfigs": "4", "unit": "°C"}], "data": [], "supplemental": []}]}]}}