{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page ?) - Nitromethane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Schuberth, H.; Z. Phys. Chem. 225O, 305-12 (1964).", "pubtype": "paper", "url": "https://doi.org/10.1515/zpch-1964-22530"}], "system": "Nitromethane with Water", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Source not specified; purity not specified; distilled over a column of 40 theoretical plates; BP = 101.2°C, $n_{D}^{20}$ = 1.3819, $\\rho^{20} = \\pu{1139 g L-1}$."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Twice distilled."}], "method": "The synthetic method and the titration method were used. No further details were reported.", "dataset": [{"series": 1, "title": "Mutual solubility of nitromethane and water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.00e+01", "significand": "2.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "3.42e-02", "significand": "3.42", "exponent": "-2", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.071e+01", "significand": "1.071", "exponent": "1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.00e+01", "significand": "2.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.932e+02", "significand": "2.932", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "9.353e-01", "significand": "9.353", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.80e+01", "significand": "9.80", "exponent": "1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.00e+01", "significand": "3.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.032e+02", "significand": "3.032", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "3.70e-02", "significand": "3.70", "exponent": "-2", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.152e+01", "significand": "1.152", "exponent": "1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.00e+01", "significand": "3.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.032e+02", "significand": "3.032", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "9.205e-01", "significand": "9.205", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.751e+01", "significand": "9.751", "exponent": "1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "4.00e+01", "significand": "4.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.132e+02", "significand": "3.132", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.15e-02", "significand": "4.15", "exponent": "-2", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.279e+01", "significand": "1.279", "exponent": "1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "4.00e+01", "significand": "4.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.132e+02", "significand": "3.132", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.975e-01", "significand": "8.975", "exponent": "-1", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "9.675e+01", "significand": "9.675", "exponent": "1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "5.00e+01", "significand": "5.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.232e+02", "significand": "3.232", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.80e-02", "significand": "4.80", "exponent": "-2", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Percent mass fraction (1)", "number": "1.459e+01", "significand": "1.459", "exponent": "1", "sigfigs": "4", "unit": "1"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "5.00e+01", "significand": "5.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.232e+02", "significand": "3.232", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - 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