{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4890/jsonld#"}], "@id": "", "generatedAt": "10-18-26 04:28:59", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4890/jsonld#", "@type": "sdo:scidataFramework", "uid": "77_134", "title": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane, 1-Nitropropane, 2-Nitropropane and oil fraction of Tuimazin crude", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "Nikolai I. Lisov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "obo:NCIT_C25206", "obo:NCIT_C75762", "qudt:GM-PER-CentiM3", "qudt:K", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The method, described in Bondarev and Kozlov [1] was used. 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Fuels Oils 4(10), 720-724 (1968)", "doi": "10.1007/bf00723114", "url": "https://doi.org/10.1007/bf00723114"}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "2-Nitropropane", "formula": "C3H7NO2                ", "casrn": "79-46-9", "iupacname": "2-nitropropane", "inchikey": "FGLBSLMDCBOPQK-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Oil fraction of Tuimazin crude", "formula": null, "casrn": "mix-06", "iupacname": "Methyl (5-chloro-2-thienyl)acetate", "inchikey": "UDCBKVJFXVVZEI-UHFFFAOYSA-N"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Nitroethane", "formula": "C2H5NO2", "casrn": "79-24-3", "iupacname": "1-nitroethane", "inchikey": "MCSAJNNLRCFZED-UHFFFAOYSA-N"}, {"@id": "substance/4/", "@type": "sdo:substance", "name": "1-Nitropropane", "formula": "C3H7NO2", "casrn": "108-03-2", "iupacname": "1-nitropropane", "inchikey": "JSZOAYXJRCEYSX-UHFFFAOYSA-N"}, {"@id": 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distillation of Tuimazin crude between 440 and 520°C; stocks obtained by division of oil fraction on silica gel by liquid chromatography", "substance#": "substance/4/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitroethane, 1-Nitropropane, 2-Nitropropane and oil fraction of Tuimazin crude", "type": "quaternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 4", "chemical#": "chemical/4/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/4/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": 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"quantity": "Refractive Index", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "1.420-1.4756"}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Pol'shinskii, V. V.; Kozlov, L. M.; Chem. Technol. Fuels Oils 1970, 6(10), 730-734.", "doi": "10.1007/bf00716432", "url": "https://doi.org/10.1007/bf00716432"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 77 (page ?) - Nitroethane, 1-Nitropropane, 2-Nitropropane and oil fraction of Tuimazin crude", "url": "https://doi.org/10.1063/1.1417522"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}