{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4824/jsonld#"}], "@id": "", "generatedAt": "08-19-26 07:31:28", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4824/jsonld#", "@type": "sdo:scidataFramework", "uid": "73_75", "title": "Solubility data from IUPAC SDS Volume 73 (page ?) - Lithium formate with Zinc formate and Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Christo Balarew", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "Stoyanka Trendafilova", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The isothermal method was used. Equilibrium was reached in 1-2 weeks. The lithium content of both phases was determined by flame photometry. The zinc content was determined complexometrically. The composition of the solid phases was determined by Schreinemakers' method.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Lithium formate", "formula": "LiCHO2", "casrn": "556-63-8", "iupacname": "lithium formate", "inchikey": "XKPJKVVZOOEMPK-UHFFFAOYSA-M"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Zinc formate", "formula": "Zn(CHO2)2", "casrn": "557-41-5", "iupacname": "zinc diformate", "inchikey": "XOBMCBQSUCOAOC-UHFFFAOYSA-L"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Lithium formate", "description": "$\\ce{LiCHO2.H2O}$ was prepared by neutralizing 85% formic acid with suprapure reagent grade $\\ce{LiOH}$. The crystals were washed with alcohol and dried at 105&deg;C over $\\ce{H2SO4}$ in a vacuum. $\\ce{Zn(CHO2)2.2H2O}$ was prepared by the reaction of 85% PA grade formic acid with $\\ce{ZnO}$. It was recrystallized twice from 1% formic acid and dried at 105&deg;C.", "substance#": "substance/1/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Lithium formate with Zinc formate and Water", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}]}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/", "datapoint/7/", "datapoint/8/", "datapoint/9/", "datapoint/10/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "73:075:001:001:001", "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.38e+00", "significand": 5.38, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.66e-01", "significand": 3.66, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/1/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "73:075:001:001:002", "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.05e+00", "significand": 3.05, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.01e+00", "significand": 3.01, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.25e-01", "significand": 6.25, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.06e-01", "significand": 2.06, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/2/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "73:075:001:001:003", "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.23e+00", "significand": 6.23, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.26e+00", "significand": 2.26, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.31e+00", "significand": 1.31, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/3/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/3/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.58e-01", "significand": 1.58, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/3/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "73:075:001:001:004", "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.76e+00", "significand": 9.76, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.90e+00", "significand": 1.9, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.13e+00", "significand": 2.13, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/4/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/4/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.38e-01", "significand": 1.38, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/4/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/4/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "73:075:001:001:005", "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.517e+01", "significand": 1.517, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.90e+00", "significand": 1.9, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.520e+00", "significand": 3.52, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.47e-01", "significand": 1.47, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/5/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "73:075:001:001:006", "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.111e+01", "significand": 2.111, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.33e+00", "significand": 2.33, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.307e+00", "significand": 5.307, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/6/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/6/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.96e-01", "significand": 1.96, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/6/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/6/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/7/", "@type": "sdo:datapoint", "uid": "73:075:001:001:007", "data": [{"@id": "datapoint/7/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/7/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.663e+01", "significand": 2.663, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/7/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/7/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.93e+00", "significand": 2.93, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/7/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/7/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.276e+00", "significand": 7.276, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/7/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/7/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.67e-01", "significand": 2.67, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/7/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/7/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/8/", "@type": "sdo:datapoint", "uid": "73:075:001:001:008", "data": [{"@id": "datapoint/8/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/8/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.755e+01", "significand": 2.755, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/8/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/8/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.86e+00", "significand": 2.86, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/8/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/8/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.620e+00", "significand": 7.62, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/8/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/8/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.64e-01", "significand": 2.64, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/8/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/8/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A + B"}}]}, {"@id": "datapoint/9/", "@type": "sdo:datapoint", "uid": "73:075:001:001:009", "data": [{"@id": "datapoint/9/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/9/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.650e+01", "significand": 2.65, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/9/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/9/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.82e+00", "significand": 1.82, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/9/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/9/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.115e+00", "significand": 7.115, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/9/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/9/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.63e-01", "significand": 1.63, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/9/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/9/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "B"}}]}, {"@id": "datapoint/10/", "@type": "sdo:datapoint", "uid": "73:075:001:001:010", "data": [{"@id": "datapoint/10/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/10/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.799e+01", "significand": 2.799, "exponent": 1, "sigfigs": 4}}, {"@id": "datapoint/10/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (2)", "value": {"@id": "datapoint/10/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/10/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/10/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.481e+00", "significand": 7.481, "exponent": 0, "sigfigs": 4}}, {"@id": "datapoint/10/datum/4/", "@type": "sdo:datum", "quantity": "Molality (2)", "value": {"@id": "datapoint/10/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/10/datum/5/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/10/datum/5/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "B"}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Itkina, L. S.; Nadzharyan, K. A.; Zh. Neorg. Khim. 24, 2283-5 (1979)."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 73 (page ?) - Lithium formate with Zinc formate and Water", "url": "https://doi.org/10.1063/1.1354207"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}