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Equilibrium was reached in six days. The lithium content of both phases was determined by flame photometry. The formate content was determined permanganometrically. The cesium content was the difference between the total formate content and the formate present as lithium formate. It was also determined by the tetraphenyl borate method. The composition of the solid phases was determined by Schreinemakers' method.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Lithium formate", "formula": "LiCHO2", "casrn": "556-63-8", "iupacname": "lithium formate", "inchikey": "XKPJKVVZOOEMPK-UHFFFAOYSA-M"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Cesium formate", "formula": "CsCHO2", "casrn": "3495-36-1", "iupacname": "cesium formate", "inchikey": "ATZQZZAXOPPAAQ-UHFFFAOYSA-M"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Lithium formate", "description": "$\\ce{LiCHO2}$ was prepared by heating PA grade $\\ce{LiCHO2.H2O}$ at 120°C. $\\ce{CsCHO2}$ was obtained by neutralizing 85% PA grade formic acid with a pure $\\ce{CsOH}$. 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