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The aluminum content was determined complexometrically by back titrating excess Trilon B with a $\\pu{0.1 N} \\ce{Pb(NO3)2}$ solution. Xylenol orange was the indicator. The formate ion content was determined permanganometrically or by titration with dilute $\\ce{NaOH}$.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Aluminum formate", "formula": "Al(CHO2)3", "casrn": "7360-53-4", "iupacname": "aluminum triformate", "inchikey": "MJWPFSQVORELDX-UHFFFAOYSA-K"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Aluminum formate", "description": "Aluminum formate was prepared by dissolving PA grade $\\ce{AlCl3.6H2O}$ and PA grade $\\ce{NaHCO3}$ at room temperature in a minimum quantity of 10% PA grade formic acid. 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"sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.67e-01", "significand": 4.67, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "A"}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "73:041:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1 related species)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "hydrolysis"}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": 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"quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.5e-01", "significand": 5.5, "exponent": -1, "sigfigs": 2}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.11e-01", "significand": 2.11, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "B"}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "73:041:001:002:003", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1 related species)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.44e+00", "significand": 1.44, "exponent": 0, "sigfigs": 3}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Percent mass fraction (1)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.4e-01", "significand": 2.4, "exponent": -1, "sigfigs": 2}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1)", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9e-02", "significand": 9.0, "exponent": -2, "sigfigs": 1}}, {"@id": "datapoint/6/datum/4/", "@type": "sdo:datum", "quantity": "Phase (solid)", "value": {"@id": "datapoint/6/datum/4/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "C"}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Chaplygina, N. M.; Babievskaya, I. Z.; Kudinov, I. B.; Zh. Neorg. Khim. 29, 2206-10 (1984)"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 73 (page ?) - Aluminum formate with Water", "url": "https://doi.org/10.1063/1.1354207"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}