{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/1047/jsonld#"}], "@id": "", "generatedAt": "04-18-26 16:58:24", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/1047/jsonld#", "@type": "sdo:scidataFramework", "uid": "38_465", "title": "Solubility data from IUPAC SDS Volume 38 (page ?) - Hexacosane with Seawater", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "David G. Shaw", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "P.A. Meyers", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "(1) and (2) were placed in a glass stoppered flask fitted with a Teflon stopcock near the bottom. The components were equilibrated by gentle shaking for 12 hrs at 25.0 \u00b1 0.1 \u00b0C. The mixture was then allowed to stand for 24 hrs. Samples removed via the stopcock were filtered with suction through 0.45 \u00b5m membrane filters to remove any hydrocarbon droplets. The filtrate was extracted three times with hexane and analyzed by gas chromatography."}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "chemname": "Hexacosane", "formula": "C26H54", "casrn": "630-01-3", "iupacname": "hexacosane", "inchikey": "HMSWAIKSFDFLKN-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "chemname": "Seawater", "formula": "H2O", "casrn": "7732-18-5(C)", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Hexacosane", "description": "Analabs, Inc., North Haven, Conn. 99+% pure hydrocarbons.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Seawater", "description": "Seawater collected from 25 m depth in Gulf of Mexico, poisoned with HgCl<sub>2</sub> sln to prevent bacterial growth, and filtered through Gelman glass fiber filter. Natural n-alkane levels too low to cause interference", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Hexacosane with Seawater", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Sutton, C.; Calder, J. A.; Environ. Sci. Technol. 1974, 8, 654-7.", "doi": "10.1021/es60092a007"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 38 (page ?) - Hexacosane with Seawater", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-38.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}